MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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In this lecture, Prof. Field explains the structure of the course, historical background, and the photoelectric effect.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the wave nature of the electron and the internal structure of an atom.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture covers the two-slit experiment, which demonstrates that light and matter can can be defined both as waves and particles. The instructor also explains the uncertainty principles.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers classical wave equations, the separation of variables, boundary conditions, and the superposition of normal modes:the pluck.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers free particle and particle in a 1D box, part of quantum mechanics.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the concepts of the 3-D box and QM separation of variables.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the classical mechanic treatment of the harmonic oscillator, the traditional quantum mechanic treatment, and time-dependent quantum mechanics.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the quantum mechanical treatment of the harmonic oscillator.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture continues the discussion of harmonic oscillators and includes information on creation and annihilation operators.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture focues on the time-dependent Schrödinger equation.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers wavepacket dynamics for harmonic oscillator and particle-in-a-box.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
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This lecture covers five postulates and a catch up and review before the exam.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the topic of Hij integrals and H matrices.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the topic of Hij integrals and H matrices.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture introduces the idea of the non-degenerate perturbation theory.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture continues exploring non-degenerate perturbation theory.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the rigid rotor and is a first glimpse at central force problems.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture covers the rigid rotor and derivation by commutation rules. Angular momentum is a central theme of this lecture.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
This lecture discusses time-dependent quantum mechanics.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
View the complete course: https://ocw.mit.edu/5-61F17
YouTube Playlist: https://www.youtube.com/playlist?list=PLUl4u3cNGP62RsEHXe48Imi9-87FzQaJg
The lecture discusses what we can learn about molecules by looking at the hydrogen atom.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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In this lecture, Professor Field talks about the hydrogen atom as a model for electronic structure. In particular, he discusses quantum number scaling effects.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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After discussing the hydrogen atom in the previous lecture, Prof. Field explores the next simplest system: the helium atom.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture explains how to evaluate matrix elements of many-electron operators, which is key to interpreting the electronic properties of atoms and molecules.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture begins the discussion on molecules and molecular orbital theory. Topics include the variational method, Born-Oppenheimer Approximation, and bonding antibonding.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture continues the discussion of molecular orbital theory and includes information about diatomic molecules.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture explains the Hückel molecular orbital theory, which determines the energies of molecular orbitals of electrons.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Robert Field
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In this lecture, Prof. Field continues the discussion of non-degenerate perturbation theory.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Troy Van Voorhis
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Guest lecturer, Prof. Troy Van Voorhis, explores electronic structure theory. This discussion includes the topic of basis sets, which are a pre-defined set of AO basis functions for each atom in the periodic table.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Troy Van Voorhis
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This lecture covers information about modern electronic structure theory. Ways of computing the energy and computational chemistry tools are discussed.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This is the first of two lectures on spectroscopy and dynamics.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This is the second of two lectures that focuses on spectroscopy and dynamics.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture discusses wavepacket dynamics and what to expect and how to approach it.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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This lecture covers intermolecular interactions, electronic spectroscopy, and the Franck-Condon principle.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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In this lecture, Prof. Robert Field explains electronic spectroscopy and photochemistry.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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In this lecture, Prof. Field talks about the discrete variable representation. He introduces the students to delta-functions.
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MIT 5.61 Physical Chemistry, Fall 2017
Instructor: Professor Robert Field
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In this final lecture, Prof. Field explains time dependence of two-level systems, with attention to density matrix and rotating wave approximation.
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Lecture 6: Vision 2 Instructor: John Gabrieli View the complete course: http://ocw.mit.edu/9-00SCS11 License: Creative Commons BY-NC-SA
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